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The standard state of an electrochemical cell is measured as 1 atm pressure for all gases and 1.0 M for all aqueous solutions.

A) True
B) False

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A Galvanic cell is an electrochemical cell in which a spontaneous chemical reaction may be used to generate an electrical current.

A) True
B) False

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The rusting witnessed in the sheet metal of a '65 Impala is an example of:


A) uniform corrosion.
B) galvanic corrosion.
C) electrolysis.
D) compounding corrosion.

E) A) and D)
F) B) and C)

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The standard hydrogen electrode (SHE) involves gaseous HCl at 1 atm being bubbled into water.

A) True
B) False

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In the decomposition of hydrogen peroxide, which atom is being reduced? H2O2( aq ) → H2( g ) + O2( g )


A) H
B) O
C) both
D) neither

E) C) and D)
F) A) and B)

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A

What is the E0 value for the Galvanic cell formed from these two half-reactions? What is the E<sup>0</sup> value for the Galvanic cell formed from these two half-reactions?   A)  +1.334 V B)  − 2.046 V C)  +2.046 V D)  +2.758 V


A) +1.334 V
B) − 2.046 V
C) +2.046 V
D) +2.758 V

E) A) and D)
F) A) and B)

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In the formation of iron (II) oxide, which species is being reduced? Fe( s ) + O2( g ) → FeO( s )


A) FeO
B) Fe2O3
C) Fe
D) O2

E) None of the above
F) A) and C)

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D

Reduction occurs at the anode of a Galvanic cell.

A) True
B) False

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Given a Galvanic cell: Given a Galvanic cell:   , the right-hand side of this notation represents the: A)  spontaneous half of the reaction. B)  oxidation 1/2 reaction. C)  anode of the cell. D)  reduction 1/2 reaction. , the right-hand side of this notation represents the:


A) spontaneous half of the reaction.
B) oxidation 1/2 reaction.
C) anode of the cell.
D) reduction 1/2 reaction.

E) A) and C)
F) A) and D)

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Secondary cells are designed to be rechargeable.

A) True
B) False

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What is the oxidation number of Mn in MnO4?


A) 1+
B) 2+
C) 7+
D) 8+

E) B) and D)
F) B) and C)

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What is the E0 value for the Galvanic cell formed from these two half-reactions? What is the E<sup>0</sup> value for the Galvanic cell formed from these two half-reactions?   A)  − 2.31 V B)  +4.33 V C)  − 1.32 V D)  +2.00 V


A) − 2.31 V
B) +4.33 V
C) − 1.32 V
D) +2.00 V

E) All of the above
F) B) and C)

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How many grams of silver are deposited at a platinum cathode in the electrolysis of AgNO3 (aq) by 5.30 amps of electric current in 4.0 hours?


A) 85.3 g
B) 42.6 g
C) 121 g
D) 188 g

E) A) and D)
F) A) and B)

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Galvanic corrosion may occur only when two different metals are in contact with one another.

A) True
B) False

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True

In a redox reaction:


A) there is a transfer of protons from one species to another.
B) electrons are created.
C) electrons are transferred between two species.
D) the reaction always moves in a reverse direction.

E) None of the above
F) All of the above

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In the formation of iron (II) oxide, which species is being reduced? Fe( s ) + O2( g ) → FeO( s )


A) FeO
B) Fe2O3
C) Fe
D) O2

E) A) and D)
F) None of the above

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Balance the following electrochemical reaction in acid: MnO4( aq ) + Zr( s ) ↔ Mn2+( aq ) + Zr2+( aq )


A) 2 MnO4( aq ) + 16H+( aq ) + 5 Zr( s ) → 2 Mn2+( aq ) + 5 Zr2+( aq ) + 8 H2O( l )
B) 2 MnO4( aq ) + 5 Zr( s ) → 2 Mn2+( aq ) + 5 Zr2+( aq )
C) MnO4( aq ) + Zr( s ) → Mn2+( aq ) + Zr2+( aq ) + 5 e
D) 2 MnO4( aq ) + 8H+( aq ) + 5 Zr( s ) → 2 Mn2+( aq ) + 5 Zr2+( aq ) + 8 H2O( l )

E) A) and B)
F) A) and D)

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Species with positive standard reduction potentials are excellent candidates for reduction reactions.

A) True
B) False

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Using the provided standard reduction potentials, which of the following cells is an example of a Galvanic cell?


A) Using the provided standard reduction potentials, which of the following cells is an example of a Galvanic cell? A)    B)    C)    D)
B) Using the provided standard reduction potentials, which of the following cells is an example of a Galvanic cell? A)    B)    C)    D)
C) Using the provided standard reduction potentials, which of the following cells is an example of a Galvanic cell? A)    B)    C)    D)
D) Using the provided standard reduction potentials, which of the following cells is an example of a Galvanic cell? A)    B)    C)    D)

E) All of the above
F) C) and D)

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Which phrase best describes the half-reaction as written? Na+ + e → Na


A) oxidation 1/2 reaction
B) reduction 1/2 reaction
C) group 2 ionization
D) two electron transfer

E) A) and B)
F) None of the above

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